2008年3月13日星期四

2 shells Mi technology

70.611Coal/Coal acting oil: The way of coal replacing automobile oil product has coal mainly to change oil and coal acting oil. Domestic supernatural China group , Yan coal group difference sets foot in is direct/Indirect liquefied50010 thousand100The scale of 10 thousand1100 million Yuan controls. Coal denotes to produce carbinol through coal gasification technology for oil , 2 shells Mi etc. product, the latter again in Chan mix petrol and diesel oil use, reach partially replacing petroleum , reduce the purpose of petroleum consumption. Change oil relative to coal , coal acting oil is ripening more on technology , therefore has relatively lower investment risk, market extends space to compare , is big

61.01 thousand( technology)The expert of reporter interview southwest chemical research institute knows that now, domestic has established operation , the 2 shells that realize industrialization Mi installation biggest scale, use domestic technology, the law of gaseous phase is110/In year,1010/Year. Is from the1010/Year. Present domestic technical2010 thousand tons, also return have no the inspection via industrialization production. Again big installation scale present domestic foundation can not do design, need to carry out installation to magnify research , must still produce via a industrialization process, then can calculate technical maturation. So, a process is not that short time can realize.

( technology)Current hair alters100The installation more than 10 thousand tons of level, and domestic design technical strength can't be done obviously, can only let foreign company does. It is this to stipulate , has broken away from the domestic reality of technical ability, on objective having encouraged transfer foreign technology.

The Henan province industrial company of chemical fertilizer endures , is perennial to produce practice, development makes a kind of 2 new shells Mi production technology: Regular bed two tower one time synthetic Frances, have realized 2 shells successfully Mi efficient industrialization production, and get national invention patent. The major advantage of this technology is to be able to use the existing factory communal project and equipment of nitrogenous fertilizer completely; Catalyst packs to fill quantity , is big, changing to lead is high , is easy to industrialize production; Investment is few , construction period is short , energy consumption is low ,Cost is low(2000Yuan following)Suitable popularization is applied. Now, the factory of nitrogenous fertilizer of our country is in the difficult condition with unitary product and low benefit , especially the most of little factories of nitrogenous fertilizer , is adjustment product structure with this technology , raises the one of better method of economic benefits. Current industrialization production 2 shells Mi method have the two steps and law of one step law. This patent will the law of one step and the law of two steps are organic to combine , have overcome the law producer goods of one step to get the outside shortcoming with big influence and higher cost , it is low to have again abandoned the law transformation rate of one step , construction period length deficiency.

The reason of East- -Three-phase bed the 2 synthetic angry shells of one step of legal system Mi, process 3 years tackle key problems in coordination, make the synthetic air of our country one step law synthesis 2 shells Mi the advanced level that reaches international similar research. Having put forward a bed of innovation 3 tower pairs do over again skill process, have drawn up to produce per year310 thousand tons of three-phase slurry bed in the 2 synthetic angry shells of one step of legal system Mi technology pack, for construction 10 thousand tons of 2 level shells Mi industrial test facilities has guidance meaning.

Domestic first cover3000Ton/2 annual shells2004Year3The end of month when4Get through all processes in beginning of the month, production acceptable 2 shell Mi product. This sign the law synthetic 2 of one step of our country shell Mi have changed over to industrialization stage of production via the laboratory issue of R%26D. Establish with 2 shells Mi is the energy system of center, now, it is efficient development to be faced with biggest challenge , 2 cheap shells Mi production technology. Liquid the 2 appearance law synthetic shells of one step Mi, especially starch form bed the law synthetic 2 of one step shell Mi technology, it is the present domestic and international new technology of developing and tackling key problems eagerly. Who gets the success of industrialization development first, who can be in leading position in the world. This is former, the form bed of thick liquid developed by the chemical department of Tsinghua University the 2 law synthetic shells of one step Mi little examination technology the technical appraisement that had been organized through national educational commission, it has international advanced level. By Chongqing Britain force burns to melt the chemical department of limited company and Tsinghua University the form bed of thick liquid of joint development the law of one step3000Ton/2 annual shells Mi the trial assembly in industrialization sets up , it is a set of demonstration installation , possesses the proprietary intellectual properties such as technology, design, installation manufacture and catalyst.

Shandong the for310/2 annual2003At the end of the year, face Yi city in Shandong province to go into operation. This is 2 present Chinese domestic biggest shells Mi production line. 2 this project shells Mi is taking coal as the production of raw material. Shandong is for a long time safe and chemical310 thousand tons of 2 shells Mi after3000Yuan within, this sign 2 shells Mi the prerequisite that has had large-scale development , it has no longer been distant dream as natural gas etc., diesel oil, liquid gas and the supplementary, substitute petrol of traditional energy. Shandong for a long time safe chemical company's preparation uses5In year,10010 thousand tons of 2 shells Mi productivity,2003Year10Month signs 2 for a long time safe10010 thousand tons of 2 shells Mi

Ning summer8310 thousand tons of 2 shells Mi project,47.8100 million Yuan. Ning summer petrochemical industry group in company , coal 4 reaches China and the second designing institute of the company of mining industry, the traffic university of Xi'an and original chemical department to reach the participations such as chemical project company cooperation. This project will produce 2 shells by coal for initial raw material Mi. Project construction will divide 2 stages, first stage production2110/Year, second6210/Year. By America trade development office8310/Annual project2004Year4Month is completed , project will soon start. Ning summer coal resource is rich, but because land place west, and neighboring province Shaanxi, Inner Mongolia and Gansu etc. are rich coal provinces , coal outside transport is very difficult. Ning summer decision develops the industries such as electric power and coal chemical engineering energetically, construction 2 large scale shells Mi factory is in which a. American government invests67.510 thousand dollars

Japanese eastern foreign project1350Ton/Day(4910/Year ), carbinol is installedDME) installationDMEUsing to make fuel and petrol contain2002Year is Lu110/2 annual2003Year8Go into operation99.69%2 high quality shells Mi. Hereafter,1010/2 annual1510/Annual carbinol will use to make 2SynetixCompany's technologyMRF-ZResponder.2005In year, go into operation in spring. The 2 shells in current construction Mi installation adopts eastern foreign project company's technology, it produces 2 shells Mi use for the first time on world to make fuel. 2 eastern foreign project company's fuel level shells Mi production process based on carbinol dehydration France, with the catalyst special, a responder may produce to be as high as25010/2 annual shells35010/The carbinol of
Actually experts have long considered to use shell Mi1Kg liquid shell200-300Around Yen, compared with.( technology)Shell Mi price is at a unchanged high2Stage: First, change natural gas and methane gas into

What haveRecently, Japanese a large scale steel company has studied produce shell in large quantities with low cost Mi new technology. The place of the key of this new technology has discovered a kind of may be the direct synthesis of raw material shell Mi, with the new catalyst that copper, zinc and alumina system become. Besides to make catalyst ample performance take affect , on synthetic method, have also made improvement. Experts think , if this technology can have perfected further, the shell produced so eventually Mi price will decrease present price1/4. Then, the automobile of diesel oil is reformed1-2Become. Because of shell Mi performance is very

60.904American air product1986Year is going to1991Year4t/DIn trial assembly sets15t/DWork1998Put forward1010T/D2 shells(Unite- 210T/D). Denmark hold general rope company to adoptProblem, and1993Year< xml:namespace prefix=st1 ns="urn:schemas-microsoft-com:office:smarttags"/>< chmetcnv w:st=on unitname=kg sourcevalue=50 hasspace=False negative=False numbertype=1 tcsc=0>50kg< chmetcnv/>/DIn trial assembly
DayNKKSince1989Year begins to use the synthetic 2 of blast furnace of coal gas shell Mi little examination, the intermediate product as synthetic petrol, the rear discovery Shaanxi factory of our country with 2 shells Mi let be civil and automobile uses effect is good, is to alter with development 2 shells Mi for last day mark1995Changing to coal< chmetcnv w:st=on unitname=kg sourcevalue=50 hasspace=False negative=False numbertype=1 tcsc=0>50kg< chmetcnv/>/dIn trial assembly< chmetcnv w:st=on unitname=mm sourcevalue=90 hasspace=False negative=False numbertype=1 tcsc=0>It is< chmetcnv/>X< chmetcnv w:st=on unitname=m sourcevalue=2 hasspace=False negative=False numbertype=1 tcsc=0>It< chmetcnv/>Starch form60% above, 2 shells90% above; And with product, it is good"Reduce the fuel"Project, when coal synthesis(Take the responsibility1992Build5t/DWork trial1999Annual formal experiment uses this mine take out to mention 2 gas synthetic shells Mi, preliminary effect is good. Especially endure a succession of examine for having a competition , and reference world is tested as a result, proof 2 shell Mi have following advantage than carbinol:
1.With coal system,H2/COIs0.5-1, to syntheticH2/COIs2; ComposeH2/COIs1Can. So, heavy whole range is littleC02Content15%; Compose 2 shells45% is helpful to use inferior
2, refering to reaction100-150atm, just end reaction air50atm, respond just air
3, it is using stage , carbinol air has weak toxicity , and is for corrosion of metals , has transparent flame , explosion scope is broad, need to notice explosion proof; 2 shells Mi have no poison , do not corrode metal and flame cyan, explosion scope is little, do good to more do fuel. Burning when leting boiler fuel the moisture of generation is easyInfluenceBoiler efficiency, unit gives1/2, it is helpful
Basis above characteristic,2000Year6Organize relevant"2 shellsDevelopStrategic"It isStudyAfter have decidedNKKMake investment200100 million100t/DPractical2003After year throws to transportApplyFull scale test, think that2005In year, the inferior field2500t/ABusiness popularizes2010Will extend
Produce70010T, greater
Value 2 shellsEnterpriseCircle is also unwillingIndustryGallop with< chsdate w:st=on year=2001 month=6 day=5 islunardate=False isrocdate=False>2001Year6Month5Day< chsdate/>Announce< chsdate w:st=on year=2005 month=6 day=21 islunardate=False isrocdate=False>6Month21Day< chsdate/>Joint"2 Japanese"Develop
1, make3100 million1Annual time carries out 2
2.If result is feasible,"2 shells Mi", when west5-6The construction140-24010T/A2 shells
3, develop4Side when the advantage of coal2006Year is establishedLPGAsk with the1.5100- 2100 million
For the role that plays renewable energy , Japanese capital university energy work studies research institute straight research uses the system of marsh gas 2 shells Mi technology. Japanese energy circle still looks ahead the future to use the production of developed rear photoelectric electrolysis water low-priced hydrogen, add 2 combustion shells in Mi the exhaust gas that etc. clean fuel producesC02, press type synthetic carbinol
Compose3H< chmetcnv w:st=on unitname=C sourcevalue=20 hasspace=False negative=False numbertype=1 tcsc=1>210C< chmetcnv/>02CH3OH10H2O
Synthetic6H< chmetcnv w:st=on unitname=C sourcevalue=22 hasspace=False negative=False numbertype=1 tcsc=1>2102C< chmetcnv/>2 CH30CH3103H20
.2 domestic

2 shells Mi production methods earliest is from the by-product in the carbinol production of high voltage shrewd Liu rear system gets , along with the extensive application of the synthetic carbinol technology of low voltage, associate reaction decreases greatly, 2 shells Mi industrial production technology develop carbinol dehydration or synthetic angry directly synthetic technology very quickly. Carbinol dehydration France includes liquid appearance carbinol France gentle appearance carbinol France, the reaction of the former when in liquid appearance goes on , carbinol is made by the thick dehydration of sulphuric acid, but since this France has installation scale, is little , equipment is perishable to lose , environmental pollution and operating condition bad etc. problem, had been superseded step by step. In recent years, 2 shells Mi demand increase is greater, countries again develop investment province and operating condition in succession well , the new technology of free from contamination, include the law of two steps and the law of one step mainly.

The law of two steps first from synthesis air system takes carbinol, then will carbinol under catalyst dehydration system takes 2 shells Mi. Before, make catalyst mainly with sulphuric acid, now adopts mostly from- Al2O3/SiO2SystemZSM-5Member sifts to make catalyst , performance

The law of one step from synthesis air direct system takes 2 shells Mi , include composing air to enter responder at the same time complete carbinol synthetic and two carbinol dehydration reactions and waters-Coal gas alternates reaction, outcome is carbinol with 2 shells Mi mixture, mixture separates by distillation 2 shells Mi, the carbinol return responder that does not respond. The law of one step is become normally with duplex catalyst with two kinds of catalyst mixture , is in which a kind of to compose carbinol catalyst, another kind is carbinol dehydration catalyst. Synthetic carbinol catalyst includesCu-Zn-Al( O)Base catalyst,BASF,S3-85AndI-CI-512Wait. Carbinol dehydrationSiO2- Al2O3,YType memberZSM-5Member sifts , mercerized zeolite.

The 2 shells of one

CO+H2- > CH3OH - H=90.7 kJ / mol( 1)

2CH3OH- > CH3OCH3+H2O - H=23.5 kJ / mol( 2)
CO+H2O- > CO2+H2- H=41.2 kJ / mol( 3)
Total3CO+3H2- > CH3OCH3+CO2- H=246.1 kJ / mol( 4)

Compared with the lawCOTransformation rate is higher than the France of two steps , but in the France of one step, because of 3 reactions must at the same time occur, and 3 reactions are the reaction of heat release , this asks the catalyst used to have very good hear resistance , has select-high under high temperature. The 2 shells of the law production of one step Mi use normally to make mellow wine Mi fuel, if want to produce , high pure degree need to still separate further to purify. Though, the transformation rate of the law of two steps is not as good as the law of one step, is high, but it has production technology maturation, installation adaptability is broad, post-treatment is simple to wait for characteristic, may directly build in carbinol manufacturer , may also build the good non carbinol manufacturer in other communal facility. Compared with the law of one step, the law synthetic process of two steps grows slightly, but two kinds of catalyst packs in different responder , does not disturb mutual. From the present tendency that technology develops , it is short that the law of one step has process , equipment efficiency high, operating pressure is low andCOThe transformation rate of one way higher characteristic, making the operating cost and cost of installation cost large decrease , synthetic 2 shell Mi production cost the law of two steps reduces substantially. Therefore on the law economy of one step, it is more reasonable, on market, it is with more competitiveness , in general the advantage with more technology.

According to technology characteristic and the appearance form in reaction process, come to divide , synthetic air one step legal system 2 shell Mi technology has the minute of two-phase law and three-phase law mainly. Two-phase law again weighs the law of gaseous phase(GPDME), three-phaseLPDME). The law of gaseous phase major when in regular bed responder goes on , compose air in solid catalyst surface to carry out reaction , compose air if use has carbon, catalyst surface meeting closes charcoal very quickly lose work , therefore the law of gaseous phase can only use rich hydrogen synthetic air(H2/COLong-range2), and when low transformation rate condition finishes drill to do ( do not the synthesis of reaction air plenty of cycles). The law major technical technology of gaseous phase has Denmark to hold general rope companyTIGASLaw and the JapaneseCOSMOThe jointASMTGLaw. Appearance lawCO,H2And 2 shell Mi is gaseous phase, inertia solvent for liquid appearance, suspending in the catalyst thin powder in solvent is firmly appearance. Because of liquid, thermal capacitance of appearance is big, therefore liquid appearance law very easy realization constant temperature operation, and catalyst particulate surface is surrounded for solvent, knot charcoal phenomenon is alleviated considerably, therefore it is raw material to use rich carbon synthetic air. Now, Chinese Tsinghua University and American air chemical company with JapanNKKCompany is being devoted to developing with thick liquid form responder from synthesis air one step law synthesis 2 shell Mi industrialization technology, and in last end of the century in century first difference has gone on examination, for 2 large-scale shells Mi production has established foundation.

2 present domestic shells Mi the technical unit of research and development has Shandong mainly the for a long time safe chemical Joint Stock Limited Company of science and technology, the chemical department of Tsinghua University and orchid melt company's research institute, Zhejiang university, Hangzhou university catalytic research institute and the Dalian of the Chinese Academy of Sciences melt thing and Taiyuan reason work university and the reason of East China work university chemical institute and chemical department southwest chemical research institute.

Shandong for a long time safe chemical Li Ji Jin and Li Qi Fu of science and technology of Joint Stock Limited Company son, is devoted to energy chemical research for a long time, tackle key problems actively 2 shells Mi technology, process relapse experiment research, when2001Annual development makes( technology)"Liquid appearance", and have2002Year7Month, the Shandong province hall organization expert of science and technology appraises this project , thinks that this production technology reaches international leading level, have solved production 2 shells Mi the international difficult problem in process.When2004Year5The month Chinese world that the State Intellectual Property Office holds patent and famous-brand fair go up , this patented technology gets golden award, Shandong the for a long time safe chemical Joint Stock Limited Company of science and technology is been by comment"10 Chinese".

( technology)The chemical department of Tsinghua University when gold gushes the management of academician takes off , development starches form bed the 2 law synthetic shells of one step Mi technology, little examination the technical appraisement that had been organized through national educational commission, have reached to have international advanced level.2003Year Tsinghua University2000The construction3000t/aIn 2 shells2004Year4The end of month isChongqing Britain force burns to melt limited company will on this foundation, develop technology to trail and be related supplemental industrialization work , and build large-scale industrialization production to install.

See from reaction result, the circulating form bed of thick liquid developed by Tsinghua University 2 shells Mi production technical result is better than the company of American air product obviouslyLPDMETMTechnologyNKKIn companyCOThe transformation rate of one2.0MPa), energyLPDMETMThe catalyst that usesH2/CORub Er than syntheticDMESelectivity. The circulating form bed of thick liquid developed by Tsinghua University 2 shells in Mi production technology adoption independently the catalyst of development, 2 shells Mi selectivity reaches94%Above, and in the operation process of test

( technology)But the 2 shells of one stepCO2, it has 1/3 inCOHad beenCO2, have not onlyCO2Emission from the angle consideration

Respond from chemistryH2AndCORub Er1:1, and general method system is angry, if is taking coal as the regular bed of raw material the coal gas that air gasification makes , is taking natural gas as raw material to adopt steam transformation or pure oxygen system the coal gas gotten by air, can't reach this requirement. Therefore willCO2Recovery uses

CO2HydrogenationDMETechnologyDMEA kind of new routeCO2It is the most rich carbon resource on theCO2Come to realizeCO2Circulating use haveCO2Hydrogenation system( technology)Make peopleCO2HydrogenationDME. So, mayCO2Hydrogenation systemCO2Transformation. Dalian chemical physical this respectCO2AndH2Reaction system carbinol and 2 shellsCO2Transformation1429%, 2 shells Mi50%Control, therefore this

3.2 domestic

2 domestic shells20Century90In times, it is first, our country has Jiangsu Wu Xian only to compose some few manufacturer productions such as chemical factory and the Wuhan factory of sulphuric acid , and scale is less, annual total output only3000Ton controls.

1994In year, the Guangdong Zhongshan2500t/a2 high pure1995Year, Chengdu China2000t/a2 shells Mi installation; Afterwards, Anhui province covers the city county factory of chemical fertilizer , Zhejiang Zhu Ji new inferior chemical company, the Guangdong river door factory of nitrogenous fertilizer and the Zhejiang justice crow solely positive chemical limited company of industry and commerce also establish one after another10002500t/a2 shells Mi installation, these 1000 tons

2002Year, Shandong the for a long time safe chemical Joint Stock Limited Company of science and technology adopts the liquid of autonomous development the appearance law engineering technology of two steps establishes5000t/a2 shells Mi2003Year10Month310T/a2 shells2003End of the year, Chongqing3000t/a2 shells Mi demonstration installation and test run goes into operation. Shandong 10 thousand tons of 2 for a long time safe chemical company's level shells Mi installation and Chongqing Britain force burn to melt the company's form bed of thick liquid the 2 law shells of one step Mi the success of installation goes into operation , sign the 2 shells of our country Mi production has the development of breakthrough, and rank among world advanced ranks.

At the20Century90Times3000t/a2 following shells Mi installation, compared with the new equipment established in recent years , scale is little , engineering technology backward, production cost is high, it is stoped production that no competitiveness and majority are in or half stop production state.

Present domestic only710T/aProduce410 thousand tons.210T/aProduce1.5Ton. The 2 shells of Chinese910T/aTake whole30%, so can say our country

In view of 2 shell Mi market prospect values , as well as 2 shells Mi the development of production technology, there are a lot of places in construction in domestic or planned construction 2 shell Mi project( technology/Scale)See from development tendency, 2 shells Mi installation scale to large scale direction development, will go to 100 thousand tons of level from 10 thousand tons of present level upgrade , and then promote million ton level; Production technology develops to the law of one step, especially liquid the appearance form bed of thick liquid the law of one step; Raw material maintains coal continuously

Now, our6Coal chemical base is planing6010 thousand tons of40The construction100The 2 biggest shells of scale on the present world of 10 thousand tons of / year Mi production line. 2 shells Mi can replace diesel oil as the fuel of automobile. It come out in large quantities can remedy the petroleum reserve of our country insufficient problem.

4, 2 shells Mi development

4.1Market

2 shells Mi is daily use industrial chemicals and chemical intermediate body etc. though profit is high, economic benefits are good , but get the restriction of market demand, now so that longer time is still impossible to become 2 shells Mi big market. Along with the development of the economy of our country, it is more rapid that petroleum consumption increases constantly, especially the demand of diesel oil increases. Our country is a petroleum stores quantity is relatively poor, the country that coal resource very much enriches , coal mine time limit is more than petroleum, how to change it using rich coal resource into clean fuel have not only used the resource advantage of our country fully with replacing petroleum products , and have important strategic meaning.

Thus it can be seen, exclude should increase the development of the product of lower reaches in the market of industrial chemicals intensity outside, 2 shells Mi industrial development should stand mainly in fuel market , this is a wide huge potential market.

4.2.Technical

Though the 2 shells of one step of legal system of our country Mi have steped solid pace, but should see clearly that on technology, we still have a lot of works to do. Since the system of scientific research of our country is being in the influence of transition stage and many factors such as the restriction of economic strength, our progress and technology of scientific research change aspect to still have a lot of problems, these metropolises directly influence us to catch the pace of world level as soon as possible.

The 2 shells of our countryA)It is advanced, efficientB)Adaptation installationC)With coal as the systemCO2Use;D)ItCOChange to lead andE)2 economic shells

4.3Build

2 shells Mi is fuel industry, it is to reach this purpose to ask product to compete with petroleum products, 2 shells Mi installation must have investment province, the price of raw material is low, the conditions such as certain scale, since the territory of our country is large, on region, should still build the production of different scale fully using place, the advantage of enterprise and the combination market of this area to install.

For large scale installation, it is rich to select in the( coal or natural gas) resource of raw material , the place with sufficient electric power builds factory, since raw material is cheap, scale of production is big, product cost is low, market competitiveness is strong. Large scale enterprise should bear the role of national energy mainstay.

2 shells Mi build is also a better choice in synthetic ammonia factory, it may manage with a view to communal project facility and the spare productivity of installing with synthetic ammonia factory and , technical person material, so, save investment greatly, since investment is few , may remedy because of the deficiency with the higher price of raw material, it is short to add transportation distance again, product cost may be still lower , can so have living space also.

At the Every place when development 2 shells in Mi industry should carry out social investigation fully, according to self condition and market demand, make judgment , prevent that blindness in investment causes loss to enterprise

60.41960.419The 2 a set of18Establish and go into operation smoothly on day in Shanghai. This signifies 2 shells Mi automobile industrialization has got new progress in Shanghai, have gotten the guarantee in the aspect of energy.

Shanghai(Group)Company is external to5000The 2 shells of139Little, drive to run. Install have99.99%The 2 shells of

The Shanghai scorch senior Window

Window

Diesel Window

Window

EngineCompare , 2 shells Mi engine10%To15%, thermal2Percentage- 3A percentage10Decibel- 15Decibel. Larger advantage is ,And evenEmission

Coal melts carbinol technology is pretty60%Above carbinol gets2005Produce570Around 10 thousand tons, part relies30The output of many 10 thousand tonses, Yan coal has invested in many coals in domestic to melt carbinol factory, too work day the carbinol project that becomes , have used local coal and burnt stove angry two resource productions carbinol, not only cost is more low, at the same time, there is the certain meaning of environmental protection.
Carbinol has been tested as new energy fuel, extensively in domestic, every index is better than petrol, 2 shells Mi have been the new energy fuel of international recognized cleaning and efficiency. Shanxi province when carbinol goes as automobile on application fuel in domestic front row, through domestic and international extensive n, carbinol does not be lower than petrol as the performance of replacing performance source, domestic has begun to have carbinol vehicle put out , 2 shells Mi have been the new energy material of international recognized and key development.

50.1040501 billionShell Mi is the material synthesises such as natural gas a kind of may burn gas, since without sulphur and carbon ash, when burning , will not leave the poisonous material of the pollutive airs such as vulcanization thing and fume, therefore very environmental protection. Shell Mi production usually divide into two steps - - first becomes natural gas and methane gas carbinol, then use catalyst again to compose shell Mi. The problem that produces so is shell Mi production cost error is high, from technology, consideration carries out plenty of productions to still have a lot of difficulties, so cause shell Mi price is always at a unchanged high level , present liquid shell of 1 kgs Mi price will be more expensive and more a lot of than diesel oil, have also obstructed use from this shell Mi is automobile fuel , generate electricity the substitute of fuel or family coal gas.( technology)But recently, expert has studied produce shell in large quantities with low cost Mi new technology, the place of its key has discovered may be the direct synthesis of raw material shell Mi, with the new catalyst that copper, zinc and alumina system become; Also improve on synthetic method, so as make catalyst ample performance its role. At the same time along with expert for shell Mi production new technology perfect further, estimating last production the shell that happens Mi price will decrease 75%May use shell from this Mi replacing diesel oil is fuel, and it need to be for the oil box of the automobile of diesel oil reform slightly with compressed pump can; At the same time because of shell Mi performance is very similar with coal gas, may use shell therefore Mi the substitute as family coal gas.

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